GBW10010a大米标准物质复(研)制及数据特征     

杨榕  顾铁新  潘含江  刘妹  周国华 《岩矿测试》2020,39(6):866-877

随着我国对生态文明建设的重视，自然资源综合调查势在必行，对生物标准物质亦提出了新的需求。当前相关调研工作已经大面积开展，自然资源综合调查、农产品与食品安全评价都需要对生物样品元素组成进行准确测试，需要以生物标准物质作为生物成分测试量值比对和溯源的基础，因此对生物基体标准物质的需求量大幅增加。大米作为主要粮食之一，其食品安全日益受到重视，对大米中的化学成分进行准确的分析测试具有重要的现实意义，因而对大米标准物质的需求量尤为突出，但目前大米成分分析标准物质已供不应求。本文严格按照《标准物质定值的通用原则及统计学原理》（JJF 1343—2012）和《地质分析标准物质的研制》（JJF 1646—2017）等相关规范要求，开展了GBW10010a大米成分分析标准物质的复（研）制工作，包括样品采集、加工制备、均匀性检验、稳定性检验、多家实验室协作定值测试及不确定度评定等关键环节。结果表明：本次复（研）制的大米标准物质定值成分多样、量值准确可靠，符合国家一级标准物质的要求。GBW10010a共定值54项主微量元素，包括Ag、Al、As、B、Ba、Be、Bi、Ca、Cd、Ce、Co、Cr、Cs、Cu、Dy、Er、Eu、Fe、Gd、Ge、Hg、Ho、K、La、Li、Ho、Mg、Mn、Mo、N、Na、Nb、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Sc、Se、Si、Sm、Sr、Tb、Th、Tl、Tm、U、V、Y、Yb、Zn，其中的39项元素给出了标准值及不确定度，包括Ag、Al、As、B、Ba、Ca、Cd、Ce、Co、Cs、Cu、Dy、Er、Fe、Hg、K、Li、Mg、Mn、Mo、N、Na、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Se、Si、Sm、Sr、Tb、Tl、Y、Yb、Zn；15项元素提供参考值，包括Be、Bi、Cr、Eu、Gd、Ge、Ho、Ho、La、Nb、Sc、Th、Tm、U、V。与原有GBW10010大米标准物质相比较，GBW10010a中As、Cd、Co、Cr、Cu、Hg、Mn、Mo、Ni、Zn等重金属元素含量显著下降，其中Cd、Cu、Zn降幅较大，分别下降约39%、43%、38.7%，一定程度上反映了农田生态环境的改善。本批标准物质定值元素总数量增加了6项，新增定值元素Ag、Nb（Nb给出参考值），并且各项元素不确定度范围整体上有所缩小，如Al、Cd、Cu、Fe、K、Mg、Mo、Na、P、Pb、Se、Zn等对生物易有影响的重要元素，表明了地质分析测试方法技术的进步及定值水平的提高。本批标准物质定值元素涵盖了具有生物效应的大部分主微量元素，适用于农业生态环境地球化学调查与评价、生物样品测试、农产品质量与食品安全评价样品测试时的分析仪器校正、分析方法评价和分析质量监控等多个领域。  相似文献   

Development of the cyclic p–y curve for a single pile in sandy soil     

Sung-Ha Baek  Joonyoung Kim  Seung-Hwan Lee 《Marine Georesources & Geotechnology》2018,36(3):351-359

Pile foundations that support transmission towers or offshore structures are dominantly subjected to cyclic lateral load induced by wind and waves. For a successful design, it is crucial to investigate the effect of cyclic lateral loads on the pile behavior that is loaded laterally. Although the p–y curve method is generally utilized to design the cyclic laterally loaded pile foundations, the effect of cyclic lateral loads on the pile has not been properly implemented with the p–y curve. This reflects a lack of consideration of the overall stiffness change in soil–pile interaction. To address this, a series of model pile tests were conducted in this study on a preinstalled aluminum flexible pile under various sandy soil conditions. The test results were used to investigate the effect of cyclic lateral loads on the p–y behavior. The cyclic p–y curve, which properly takes into account this effect, was developed as a hyperbolic function. Pseudo-static analysis was also conducted with the proposed cyclic p–y curve, which showed that it was able to properly simulate cyclic laterally loaded pile behavior in sandy soil.  相似文献   

The recognition of former melt flux through high‐strain zones          下载免费PDF全文

Catherine A. Stuart  Sandra Piazolo  Nathan R. Daczko 《Journal of Metamorphic Geology》2018,36(8):1049-1069

High‐strain zones are potential pathways of melt migration through the crust. However, the identification of melt‐present high‐strain deformation is commonly limited to cases where the interpreted volume of melt “frozen” within the high‐strain zone is high (>10%). In this contribution, we examine high‐strain zones in the Pembroke Granulite, an otherwise low‐strain outcrop of volcanic arc lower crust exposed in Fiordland, New Zealand. These high‐strain zones display compositional layering, flaser‐shaped mineral grains, and closely spaced foliation planes indicative of high‐strain deformation. Asymmetric leucosome surrounding peritectic garnet grains suggest deformation was synchronous with minor amounts of in situ partial melting. High‐strain zones lack typical mylonite microstructures and instead display typical equilibrium microstructures, such as straight grain boundaries, 120° triple junctions, and subhedral grain shapes. We identify five key microstructures indicative of the former presence of melt within the high‐strain zones: (a) small dihedral angles of interstitial phases; (b) elongate interstitial grains; (c) small aggregates of quartz grains with xenomorphic plagioclase grains connected in three dimensions; (d) fine‐grained, K‐feldspar bearing, multiphase aggregates with or without augite rims; and (e) mm‐ to cm‐scale felsic dykelets. Preservation of key microstructures indicates that deformation ceased as conditions crossed the solidus, breaking the positive feedback loop between deformation and the presence of melt. We propose that microstructures indicative of the former presence of melt, such as the five identified above, may be used as a tool for recognising rocks formed during melt‐present high‐strain deformation where low (<5%) volumes of leucosome are “frozen” within the high‐strain zone.  相似文献   

不同厚度饱和砂土中群桩结构动力响应试验研究   总被引：2，自引：2，他引：0       下载免费PDF全文

李雨润  强东峰  邹泽  刘荟达  王海 《地震工程学报》2018,40(4):625-630

液化土中桩基础动力响应规律一直是工程抗震领域关注的热点问题。本文基于非液化砂土和不同厚度饱和砂土中的2×2群桩结构模型振动台试验,通过输入一定峰值加速度和频率的正弦波,对群桩在非液化土层和两种不同厚度饱和砂土层中的横向动力响应特性进行振动台试验研究。研究结果表明:在正弦波输入情况下,非液化砂土中群桩承台加速度和位移时程与台面输入时程相比,波形变化规律与峰值大小均相差不大;而对两种不同厚度饱和砂土中承台加速度和位移峰值放大较多,在相对较薄的饱和砂土中群桩承台加速度峰值较台面输入放大了1.83倍,较台面输出位移峰值放大了1.58倍;在相对较厚的饱和砂土中承台加速度和位移峰值则分别放大了2.18倍和1.91倍,说明在相同输入条件下,较厚的饱和砂土在发生液化后群桩承台的动力响应更加显著。  相似文献   

Effect of sand on the vacuum consolidation of dredged slurry     

Jun Wang  Yuanqiang Cai  Xueyu Geng  Fengqi Xu 《Marine Georesources & Geotechnology》2018,36(2):238-244

Vacuum preloading is often used to improve the geotechnical properties of dredged slurry. Although the performance of this method has improved with rapidly developing technology, soil columns usually formed on the drainage boundary induce the decrease of permeability around the boundary, thereby limiting the further development of this method. To address this issue, this paper proposes a method for pretreating the slurry combined with sand prior to vacuum consolidation. This method partially replaces the fine particles with sand to reduce the formation of soil columns. Two groups of vacuum preloading tests were performed to investigate the effect of sand content and sand grain size on the vacuum consolidation of dredged slurry. The test results revealed that for a given sand grain size, increasing the sand content of the sand–slurry mixture increased the pore water drainage and accelerated the dissipation of pore water pressure, thereby increasing the vane shear strength. In contrast, for a constant sand content, the samples containing coarse sand exhibited increased pore water drainage and accelerated dissipation of pore water pressure, thereby increasing the vane shear strength of the soil.  相似文献   

筒型桩靴在饱和砂土中的贯入阻力研究          下载免费PDF全文

吴曲楠  刘润  张海洋  王宇飞 《地震工程学报》2018,40(6):1183-1190

桩靴贯入阻力的准确预测是自升式钻井平台安全作业的前提。通过小比尺模型试验,研究饱和砂土中桩靴贯入速度对筒型桩靴插桩性能的影响,并基于地基承载力理论提出筒型桩靴贯入阻力的计算方法,进而采用CEL有限元方法模拟筒型桩靴的贯入过程,并与试验结果进行比较。研究发现:当模型试验中桩靴贯入速度在0.1～0.3mm/s时,桩靴的贯入可看作是准静态过程,此时贯入阻力变化不大,采用基于地基承载力理论中的Hansen公式和Vesic公式可较为准确地计算出对应某一深度的贯入阻力;CEL有限元方法可有效模拟筒型桩靴的贯入过程,当桩靴的贯入速度为0.1～0.3mm/s时,数值模拟结果与试验结果吻合较好。  相似文献   

珠江三角洲海相沉积软土压缩和剪切变形特性试验研究   总被引：3，自引：0，他引：3       下载免费PDF全文

张岩  耿济世  毛磊  刘芙荣 《地震工程学报》2018,40(4):745-751

为了研究近代海相沉积软土的变形特征,本文对珠江三角洲河口地区的全新世海相沉积的软土进行了室内单轴压缩与不同围压下作用下的三轴固结不排水(CU)、不固结不排水(UU)的剪切试验。试验结果表明:原状土和重塑土样的孔隙比随压力的增大而下降,且与加压方式有密切关系,加压幅度越小,土的扰动破坏越小;原状土样固结系数随着压力增加而递减,整体近似符合指数函数分布,重塑土样固结系数随着压力增加逐渐增大,整体近似符合线性函数分布。在相同的固结压力下,原状土样的强度低于重塑土样的强度。土样的应力应变曲线为应变硬化型,且围压对重塑土的影响小于原状土。  相似文献   

Analytical and empirical models for predicting the drift capacity of modern unreinforced masonry walls     

Bastian Valentin Wilding  Katrin Beyer 《地震工程与结构动力学》2018,47(10):2012-2031

Displacement‐based seismic assessment of buildings containing unreinforced masonry (URM) walls requires as input, among others, estimates of the in‐plane drift capacity at the considered limit states. Current codes assess the drift capacity of URM walls by means of empirical models with most codes relating the drift capacity to the failure mode and wall slenderness. Comparisons with experimental results show that such relationships result in large scatter and usually do not provide satisfactory predictions. The objective of this paper is to determine trends in drift capacities of modern URM walls from 61 experimental tests and to investigate whether analytical models could lead to more reliable estimates of the displacement capacity than the currently used empirical models. A recently developed analytical model for the prediction of the ultimate drift capacity for both shear and flexure controlled URM walls is introduced and simplified into an equation that is suitable for code implementation. The approach follows the idea of plastic hinge models for reinforced concrete or steel structures. It explicitly considers the influence of crushing due to flexural or shear failure in URM walls and takes into account the effect of kinematic and static boundary conditions on the drift capacity. Finally, the performance of the analytical model is benchmarked against the test data and other empirical formulations. It shows that it yields significantly better estimates than empirical models in current codes. The paper concludes with an investigation of the sensitivity of the ultimate drift capacity to the wall geometry, static, and kinematic boundary conditions.  相似文献   

广州市轨道交通二十一号线工程路基抗震性测试研究   总被引：1，自引：0，他引：1       下载免费PDF全文

李同安 《地震工程学报》2018,40(4):759-764

传统路基动模量法大都进行单路基抗震性能分析,缺乏复合路基抗震性能分析,存在较高的偏差。对广州市轨道交通二十一号线工程路基抗震性进行测试,分析该地地质条件后,通过标准贯入实验法判断原始路基土质液化情况,使用瑞典条分法测试原始路基的抗震性能,判别出该路基液化土层滑动安全系数低、抗震稳定性差,应对其进行复合路基加固。通过圆弧滑动法对加固后的复合路基中碎石桩桩网结构路基以及CFG桩桩网结构路基进行抗震性测试。实验结果表明,所提方法抗干扰性能强且测试结果精度高。  相似文献   

Coordinative similitude law considering fluid‐structure interaction for underwater shaking table tests     

Zhong‐Xian Li  Kun Wu  Yundong Shi  Ning Li  Yang Ding 《地震工程与结构动力学》2018,47(11):2315-2332

Generally, when a model is made of the same material as the prototype in shaking table tests, the equivalent material density of the scaled model is greater than that of the prototype because mass is added to the model to satisfy similitude criteria. When the water environment is modeled in underwater shaking table tests, however, it is difficult to change the density of water. The differences in the density similitude ratios of specimen materials and water can affect the similitude ratios of the hydrodynamic and wave forces with those of other forces. To solve this problem, a coordinative similitude law is proposed for underwater shaking table tests by adjusting the width of the upstream face of the model or the wave height in the model test to match the similitude ratios of hydrodynamic and wave forces with those of other forces. The designs of the similitude relations were investigated for earthquake excitation, wave excitation, and combined earthquake and wave excitation conditions. Series of numerical simulations and underwater shaking table tests were performed to validate the proposed coordinative similitude law through a comparison of coordinative model and conventional model designed based on the coordinative similitude law and traditional artificial mass simulation, respectively. The results show that the relative error was less than 10% for the coordinative model, whereas it reached 80% for the conventional model. The coordinative similitude law can better reproduce the dynamic responses of the prototype, and thus, this similitude law can be used in underwater shaking table tests.  相似文献